Sun exposure changes chemical fate of littered face masks

Masks physically degrade into nanoplastics but also chemically change with exposure to sunlight and metals in the surrounding environment

Leah Shaffer 07.31.2025

The ubiquitous face masks discarded during the COVID-19 pandemic break down into microplastics and face further chemical changes, affecting its transport in aquatic environments. (Image: Generated in Adobe by Young-Shin Jun)

Facebook Twitter Linkedin Email

The face masks worn and discarded during the COVID-19 pandemic have an uncertain fate. Their physical damage to the environment and potential to trap organisms in ecosystems are significant concerns, but these are not the only issues. New research shows that the surrounding environment can change the chemical nature of the mask materials just as those materials can change the surrounding environment.

Disposable face masks, composed of polypropylene, can degrade into micro- and nanoplastics under sunlight, producing reactive oxygen species, highly potent oxidizing agents that can oxidize other environmental components and trigger unexpected reactions.

Recent research conducted by engineers at Washington University in St. Louis, led by Young-Shin Jun, professor of energy, environmental and chemical engineering at the McKelvey School of Engineering, highlights the multipronged pollution problem posed by discarded face masks.

Ping-I (Dennis) Chou and Zhenwei Gao, both PhD graduates of the McKelvey School of Engineering, are co-first authors of the work published in the Journal of Hazardous Materials. Their research started with a simple question: What happens to all those littered masks?

The study provides new insights about the significant chemical changes that occur when face masks are exposed to sunlight, water, and trace metal ions.

Masks degrade into nanoplastics and produce reactive oxygen species, Jun said. These newly formed, highly reactive oxidizing agents interact with metal ions, causing fast formation (within a few hours) of manganese oxide on the plastic particles, Jun explained.

She added that, this study evaluated manganese ions because of its prevalence in the environment and applicability to other highly sensitive trace elements.

“These chemical reactions can change the reactivity and transport of these mask materials,” Jun said, “and thus how the materials will distribute will also change, something that has been generally overlooked.”

The environmental impact of face masks is concerning given the 2020 estimate that 1.56 million face masks entered the ocean. Manganese and iron drive various biogeochemical reactions and affect the surface chemistry of those materials. The interaction between these “redox elements” and plastic materials can influence the fate of both the plastics and trace metal species.

“They could alter the fate of trace metals, and simultaneously, trace metals could alter the fate of microplastics,” Jun added.

Also, among their findings: exposure to sunlight is required for that ultrafast manganese oxide formation—it takes only a few hours for the metal oxide layer to form on plastic particles and change how nanoplastics interact and move in the environment.

In the future, Jun and her research team will explore how organic components in aquatic environments affect the transformation and transport of pollutants from face masks. She is also interested in how biofilms of microbes interact with metal-coated nanoplastics and the role of different polymer structures in plastic waste in influencing the fate and transport those reactive metal ions.

She emphasizes the importance of awareness, noting that although trash can be quickly moved out of sight, it should not move out of mind.

“Abandoning and forgetting plastics is not a solution. Plastics not only cause physical damage but also introduce chemical changes into environmental systems,” Jun said.

“Better understanding of the reactions on the nanoscale interfaces between plastics and aquatic environments is key to addressing this challenge, and it could yield some unexpected benefits,” she said.

The chemical reaction principles discovered here could help in development of sustainable energy materials. As they understand how manganese and polymers interact, it could inform development of better supercapacitors or electrode materials.

Her ultimate goal is to transform the knowledge that her team learned from studying trash is to create valuable treasures, “especially energy materials that are environmentally benign and energy efficient,” Jun added.

Chou PI, Gao Z, Jung M, Song, M, Jun YS. Photolysis of disposable face masks facilitates abiotic manganese oxide formation. Journal of Hazardous Materials. Online June 2025.

https://doi.org/10.1016/j.jhazmat.2025.138246.

This research was supported by the National Science Foundation (CHE-1905077). The work performed at the Center for Nanoscale Materials, a U.S. Department of Energy Office of Science User Facility, was supported by the U.S. DOE, Office of Basic Energy Sciences, under Contract No. DE-AC02–06CH11357.

The McKelvey School of Engineering at Washington University in St. Louis promotes independent inquiry and education with an emphasis on scientific excellence, innovation and collaboration without boundaries. McKelvey Engineering has top-ranked research and graduate programs across departments, particularly in biomedical engineering, environmental engineering and computing, and has one of the most selective undergraduate programs in the country. With 165 full-time faculty, 1,524 undergraduate students, 1,554 graduate students and 22,000 living alumni, we are working to solve some of society’s greatest challenges; to prepare students to become leaders and innovate throughout their careers; and to be a catalyst of economic development for the St. Louis region and beyond.